Solution-processed nanostructured benzoporphyrin with polycarbonate binder for photovoltaics.
نویسندگان
چکیده
Figure 1 . (a) Chemical transformation of BP precursor (CP) to benzoporphyrin (BP) during annealing; (b) standard BP OPV device; (c) TGA analysis of PC and CP; (d) schematic of processing method used to form fi lms of BP for morphology analysis. Organic photovoltaics (OPV) based on bulk heterojunctions (BHJs) have effi ciencies above 7% [ 1 , 2 ] and can be processed from solution at potentially low cost. [ 3 ] BHJs comprise a blend of an electron donor and an electron acceptor in a phase separated morphology that provides a large interfacial area for photogeneration of electron-hole pairs. [ 4 ] The highest performance OPVs currently comprise blends of semiconducting polymers and fullerenes, such as [6,6]-phenyl-C 61 -butyric acid methyl ester (PCBM). [ 4 ] Despite their performance in BHJs, semiconducting polymers often take many complicated steps to synthesize and may be diffi cult to purify. [ 5 , 6 ]
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ورودعنوان ژورنال:
- Advanced materials
دوره 23 20 شماره
صفحات -
تاریخ انتشار 2011